Catalytic two-electron reduction of dioxygen catalysed by metal-free [14]triphyrin(2.1.1)

The catalytic two-electron reduction of dioxygen (O(2)) by octamethylferrocene (Me(8)Fc) occurs with a metal-free triphyrin (HTrip) in the presence of perchloric acid (HClO(4)) in benzonitrile (PhCN) at 298 K to yield Me(8)Fc(+) and H(2)O(2). Detailed kinetic analysis has revealed that the catalytic...

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Detalles Bibliográficos
Autores principales: Mase, Kentaro, Ohkubo, Kei, Xue, Zhaoli, Yamada, Hiroko, Fukuzumi, Shunichi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6054055/
https://www.ncbi.nlm.nih.gov/pubmed/30090268
http://dx.doi.org/10.1039/c5sc02465j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6054055/
https://www.ncbi.nlm.nih.gov/pubmed/30090268
http://dx.doi.org/10.1039/c5sc02465j

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