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Catalytic two-electron reduction of dioxygen catalysed by metal-free [14]triphyrin(2.1.1)
The catalytic two-electron reduction of dioxygen (O(2)) by octamethylferrocene (Me(8)Fc) occurs with a metal-free triphyrin (HTrip) in the presence of perchloric acid (HClO(4)) in benzonitrile (PhCN) at 298 K to yield Me(8)Fc(+) and H(2)O(2). Detailed kinetic analysis has revealed that the catalytic...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6054055/ https://www.ncbi.nlm.nih.gov/pubmed/30090268 http://dx.doi.org/10.1039/c5sc02465j |