Phosphine and carbene azido-cations: [(L)N(3)](+) and [(L)(2)N(3)](+)

The cationic N(3)-species [(p-HC(6)F(4))(3)PN(3)](+) (1) featuring a perfluoro-arene phosphonium group serves as a N(3)(+)-source in stoichiometric reactions with several Lewis bases (L) allowing for the stepwise formation of [(L)N(3)](+) and [(L)(2)N(3)](+) cations (L = phosphine, carbene) with lib...

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Detalles Bibliográficos
Autores principales: Winkelhaus, Daniel, Holthausen, Michael H., Dobrovetsky, Roman, Stephan, Douglas W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6054069/
https://www.ncbi.nlm.nih.gov/pubmed/30090255
http://dx.doi.org/10.1039/c5sc02336j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6054069/
https://www.ncbi.nlm.nih.gov/pubmed/30090255
http://dx.doi.org/10.1039/c5sc02336j

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