Phosphine and carbene azido-cations: [(L)N(3)](+) and [(L)(2)N(3)](+)

The cationic N(3)-species [(p-HC(6)F(4))(3)PN(3)](+) (1) featuring a perfluoro-arene phosphonium group serves as a N(3)(+)-source in stoichiometric reactions with several Lewis bases (L) allowing for the stepwise formation of [(L)N(3)](+) and [(L)(2)N(3)](+) cations (L = phosphine, carbene) with lib...

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Autores principales: Winkelhaus, Daniel, Holthausen, Michael H., Dobrovetsky, Roman, Stephan, Douglas W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6054069/
https://www.ncbi.nlm.nih.gov/pubmed/30090255
http://dx.doi.org/10.1039/c5sc02336j
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author Winkelhaus, Daniel
Holthausen, Michael H.
Dobrovetsky, Roman
Stephan, Douglas W.
author_facet Winkelhaus, Daniel
Holthausen, Michael H.
Dobrovetsky, Roman
Stephan, Douglas W.
author_sort Winkelhaus, Daniel
collection PubMed
description The cationic N(3)-species [(p-HC(6)F(4))(3)PN(3)](+) (1) featuring a perfluoro-arene phosphonium group serves as a N(3)(+)-source in stoichiometric reactions with several Lewis bases (L) allowing for the stepwise formation of [(L)N(3)](+) and [(L)(2)N(3)](+) cations (L = phosphine, carbene) with liberation of (p-HC(6)F(4))(3)P. X-Ray diffraction analysis and computational studies provide insight into the bonding in these remarkably stable azido-cations.
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spelling pubmed-60540692018-08-08 Phosphine and carbene azido-cations: [(L)N(3)](+) and [(L)(2)N(3)](+) Winkelhaus, Daniel Holthausen, Michael H. Dobrovetsky, Roman Stephan, Douglas W. Chem Sci Chemistry The cationic N(3)-species [(p-HC(6)F(4))(3)PN(3)](+) (1) featuring a perfluoro-arene phosphonium group serves as a N(3)(+)-source in stoichiometric reactions with several Lewis bases (L) allowing for the stepwise formation of [(L)N(3)](+) and [(L)(2)N(3)](+) cations (L = phosphine, carbene) with liberation of (p-HC(6)F(4))(3)P. X-Ray diffraction analysis and computational studies provide insight into the bonding in these remarkably stable azido-cations. Royal Society of Chemistry 2015-11-01 2015-07-21 /pmc/articles/PMC6054069/ /pubmed/30090255 http://dx.doi.org/10.1039/c5sc02336j Text en This journal is © The Royal Society of Chemistry 2015 https://creativecommons.org/licenses/by/3.0/This article is freely available. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (CC BY 3.0)
spellingShingle Chemistry
Winkelhaus, Daniel
Holthausen, Michael H.
Dobrovetsky, Roman
Stephan, Douglas W.
Phosphine and carbene azido-cations: [(L)N(3)](+) and [(L)(2)N(3)](+)
title Phosphine and carbene azido-cations: [(L)N(3)](+) and [(L)(2)N(3)](+)
title_full Phosphine and carbene azido-cations: [(L)N(3)](+) and [(L)(2)N(3)](+)
title_fullStr Phosphine and carbene azido-cations: [(L)N(3)](+) and [(L)(2)N(3)](+)
title_full_unstemmed Phosphine and carbene azido-cations: [(L)N(3)](+) and [(L)(2)N(3)](+)
title_short Phosphine and carbene azido-cations: [(L)N(3)](+) and [(L)(2)N(3)](+)
title_sort phosphine and carbene azido-cations: [(l)n(3)](+) and [(l)(2)n(3)](+)
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6054069/
https://www.ncbi.nlm.nih.gov/pubmed/30090255
http://dx.doi.org/10.1039/c5sc02336j
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AT holthausenmichaelh phosphineandcarbeneazidocationsln3andl2n3
AT dobrovetskyroman phosphineandcarbeneazidocationsln3andl2n3
AT stephandouglasw phosphineandcarbeneazidocationsln3andl2n3

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