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Phosphine and carbene azido-cations: [(L)N(3)](+) and [(L)(2)N(3)](+)
The cationic N(3)-species [(p-HC(6)F(4))(3)PN(3)](+) (1) featuring a perfluoro-arene phosphonium group serves as a N(3)(+)-source in stoichiometric reactions with several Lewis bases (L) allowing for the stepwise formation of [(L)N(3)](+) and [(L)(2)N(3)](+) cations (L = phosphine, carbene) with lib...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6054069/ https://www.ncbi.nlm.nih.gov/pubmed/30090255 http://dx.doi.org/10.1039/c5sc02336j |