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Ligand survey results in identification of PNP pincer complexes of iridium as long-lived and chemoselective catalysts for dehydrogenative borylation of terminal alkynes

Following the report on the successful use of SiNN pincer complexes of iridium as catalysts for dehydrogenative borylation of terminal alkynes (DHBTA) to alkynylboronates, this work examined a wide variety of related pincer ligands in the supporting role in DHBTA. The ligand selection included both...

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Detalles Bibliográficos
Autores principales: Lee, Chun-I, DeMott, Jessica C., Pell, Christopher J., Christopher, Alyson, Zhou, Jia, Bhuvanesh, Nattamai, Ozerov, Oleg V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6054099/
https://www.ncbi.nlm.nih.gov/pubmed/30090274
http://dx.doi.org/10.1039/c5sc02161h