A T-shaped Ni[κ(2)-(CF(2))(4)–] NHC complex: unusual C(sp(3))–F and M–C(F) bond functionalization reactions

A T-shaped octafluoronickelacyclopentane–NHC complex is prepared and characterized. While the solid-state structure includes a weak isopropyl-CH(3) agostic interaction, the reactivity of this complex with Lewis- and Brønsted acids is clearly enhanced by its low coordination number. Reaction with Me(...

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Detalles Bibliográficos
Autores principales: Andrella, Nicholas O., Sicard, Alexandre J., Gorelsky, Serge I., Korobkov, Ilia, Baker, R. Tom
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6054117/
https://www.ncbi.nlm.nih.gov/pubmed/30090259
http://dx.doi.org/10.1039/c5sc01886b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6054117/
https://www.ncbi.nlm.nih.gov/pubmed/30090259
http://dx.doi.org/10.1039/c5sc01886b

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