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Radical chain repair: The hydroalkylation of polysubstituted unactivated alkenes

The concept of repair is widely used by nature to heal molecules such as proteins, lipids, sugars, and DNA that are damaged by hydrogen atom abstraction resulting from oxidative stress. We show that this strategy, rather undocumented in the field of synthetic organic chemistry, can be used in a radi...

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Detalles Bibliográficos
Autores principales: Povie, Guillaume, Suravarapu, Sankar Rao, Bircher, Martin Peter, Mojzes, Melinda Meyer, Rieder, Samuel, Renaud, Philippe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Association for the Advancement of Science 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6054511/
https://www.ncbi.nlm.nih.gov/pubmed/30035230
http://dx.doi.org/10.1126/sciadv.aat6031