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Donor‐influenced Structure–Activity Correlations in Stoichiometric and Catalytic Reactions of Lithium Monoamido‐Monohydrido‐Dialkylaluminates

A series of heteroleptic monoamido‐monohydrido‐dialkylaluminate complexes of general formula [iBu(2)AlTMPHLi⋅donor] were synthesized and characterised in solution and in the solid state. Applying these complexes in catalytic hydroboration reactions with representative aldehydes and ketones reveals t...

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Detalles Bibliográficos
Autores principales: Lemmerz, Lara E., McLellan, Ross, Judge, Neil R., Kennedy, Alan R., Orr, Samantha A., Uzelac, Marina, Hevia, Eva, Robertson, Stuart D., Okuda, Jun, Mulvey, Robert E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6055685/
https://www.ncbi.nlm.nih.gov/pubmed/29697160
http://dx.doi.org/10.1002/chem.201801541