A Very Short Uranium(IV)–Rhodium(I) Bond with Net Double‐Dative Bonding Character

Reaction of [U{C(SiMe(3))(PPh(2))}(BIPM)(μ‐Cl)Li(TMEDA)(μ‐TMEDA)(0.5)](2) (BIPM=C(PPh(2)NSiMe(3))(2); TMEDA=Me(2)NCH(2)CH(2)NMe(2)) with [Rh(μ‐Cl)(COD)](2) (COD=cyclooctadiene) affords the heterotrimetallic U(IV)−Rh(I) (2) complex [U(Cl)(2){C(PPh(2)NSiMe(3))(PPh[C(6)H(4)]NSiMe(3))}{Rh(COD)}{Rh(CH(Si...

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Detalles Bibliográficos
Autores principales: Lu, Erli, Wooles, Ashley J., Gregson, Matthew, Cobb, Philip J., Liddle, Stephen T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6055764/
https://www.ncbi.nlm.nih.gov/pubmed/29665209
http://dx.doi.org/10.1002/anie.201803493

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6055764/
https://www.ncbi.nlm.nih.gov/pubmed/29665209
http://dx.doi.org/10.1002/anie.201803493

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