Cargando…

A Very Short Uranium(IV)–Rhodium(I) Bond with Net Double‐Dative Bonding Character

Reaction of [U{C(SiMe(3))(PPh(2))}(BIPM)(μ‐Cl)Li(TMEDA)(μ‐TMEDA)(0.5)](2) (BIPM=C(PPh(2)NSiMe(3))(2); TMEDA=Me(2)NCH(2)CH(2)NMe(2)) with [Rh(μ‐Cl)(COD)](2) (COD=cyclooctadiene) affords the heterotrimetallic U(IV)−Rh(I) (2) complex [U(Cl)(2){C(PPh(2)NSiMe(3))(PPh[C(6)H(4)]NSiMe(3))}{Rh(COD)}{Rh(CH(Si...

Descripción completa

Detalles Bibliográficos
Autores principales:	Lu, Erli, Wooles, Ashley J., Gregson, Matthew, Cobb, Philip J., Liddle, Stephen T.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2018
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6055764/ https://www.ncbi.nlm.nih.gov/pubmed/29665209 http://dx.doi.org/10.1002/anie.201803493

Ejemplares similares

Double dative bond between divalent carbon(0) and uranium
por: Su, Wei, et al.
Publicado: (2018)

Silyl‐Phosphino‐Carbene Complexes of Uranium(IV)
por: Lu, Erli, et al.
Publicado: (2018)

Mesoionic Carbene Complexes of Uranium(IV) and Thorium(IV)
por: Seed, John A., et al.
Publicado: (2022)

Uranium rhodium bonding in heterometallic complexes
por: Hlina, J. A., et al.
Publicado: (2017)

Emergence of comparable covalency in isostructural cerium(iv)– and uranium(iv)–carbon multiple bonds
por: Gregson, Matthew, et al.
Publicado: (2016)

Arsolyl-supported intermetallic dative bonding
por: Kirk, Ryan M., et al.
Publicado: (2022)

Evidence for ligand- and solvent-induced disproportionation of uranium(IV)
por: Du, Jingzhen, et al.
Publicado: (2021)

Breaking a dative bond with mechanical forces
por: Chen, Pengcheng, et al.
Publicado: (2021)

Beyond the Classical Electron‐Sharing and Dative Bond Picture: Case of the Spin‐Polarized Bond
por: Salvador, Pedro, et al.
Publicado: (2020)

Formation of polyrotaxane crystals driven by dative boron–nitrogen bonds
por: Xiao, Xuedong, et al.
Publicado: (2023)

Uranium–nitride chemistry: uranium–uranium electronic communication mediated by nitride bridges
por: King, David M., et al.
Publicado: (2022)

Uranium(III)-carbon multiple bonding supported by arene δ-bonding in mixed-valence hexauranium nanometre-scale rings
por: Wooles, Ashley J., et al.
Publicado: (2018)

The stability of covalent dative bond significantly increases with increasing solvent polarity
por: Lo, Rabindranath, et al.
Publicado: (2022)

The Dimethylbismuth Cation: Entry Into Dative Bi−Bi Bonding and Unconventional Methyl Exchange
por: Ramler, Jacqueline, et al.
Publicado: (2021)

Heavy-Atom Tunneling in the Covalent/Dative Bond Complexation of Cyclo[18]carbon–Piperidine
por: Nandi, Ashim, et al.
Publicado: (2022)

Uranium(iv) terminal hydrosulfido and sulfido complexes: insights into the nature of the uranium–sulfur bond
por: Rosenzweig, Michael W., et al.
Publicado: (2016)

d–d Dative Bonding Between Iron and the Alkaline‐Earth Metals Calcium, Strontium, and Barium
por: Stegner, Philipp, et al.
Publicado: (2020)

Terminal uranium(V)-nitride hydrogenations involving direct addition or Frustrated Lewis Pair mechanisms
por: Chatelain, Lucile, et al.
Publicado: (2020)

An Allyl Uranium(IV) Sandwich Complex: Are ϕ Bonding Interactions Possible?
por: Popov, Ivan A., et al.
Publicado: (2022)

Dative B←N bonds based crystalline organic framework with permanent porosity for acetylene storage and separation
por: Wang, Weize, et al.
Publicado: (2022)

Evidence for single metal two electron oxidative addition and reductive elimination at uranium
por: Gardner, Benedict M., et al.
Publicado: (2017)

Thorium- and uranium-azide reductions: a transient dithorium-nitride versus isolable diuranium-nitrides
por: Du, Jingzhen, et al.
Publicado: (2019)

Raman Spectroscopic and Quantum Chemical Investigation of the Pyridine-Borane Complex and the Effects of Dative Bonding on the Normal Modes of Pyridine
por: Lambert, Ethan C., et al.
Publicado: (2022)

Facile Access to Dative, Single, and Double Silicon−Metal Bonds Through M−Cl Insertion Reactions of Base‐Stabilized Si(II) Cations
por: Frisch, Philipp, et al.
Publicado: (2020)

Thorium–phosphorus triamidoamine complexes containing Th–P single- and multiple-bond interactions
por: Wildman, Elizabeth P., et al.
Publicado: (2016)

Dehydrogenative Double C−H Bond Activation in a Germylene‐Rhodium Complex
por: Bajo, Sonia, et al.
Publicado: (2021)

Author Correction: Thorium–phosphorus triamidoamine complexes containing Th–P single- and multiple-bond interactions
por: Wildman, Elizabeth P., et al.
Publicado: (2023)

Thorium-nitrogen multiple bonds provide evidence for pushing-from-below for early actinides
por: Du, Jingzhen, et al.
Publicado: (2019)

Actinide–Pnictide (An−Pn) Bonds Spanning Non‐Metal, Metalloid, and Metal Combinations (An=U, Th; Pn=P, As, Sb, Bi)
por: Rookes, Thomas M., et al.
Publicado: (2017)

Rare‐Earth‐ and Uranium‐Mesoionic Carbenes: A New Class of f‐Block Carbene Complex Derived from an N‐Heterocyclic Olefin
por: Seed, John A., et al.
Publicado: (2017)

Effects of ligands on the migratory insertion of alkenes into rhodium–oxygen bonds
por: Richers, Casseday P., et al.
Publicado: (2020)

Cooperative dihydrogen activation with unsupported uranium–metal bonds and characterization of a terminal U(iv) hydride
por: Ward, Robert J., et al.
Publicado: (2023)

Heteroleptic actinocenes: a thorium(iv)–cyclobutadienyl–cyclooctatetraenyl–di-potassium-cyclooctatetraenyl complex
por: Boronski, Josef T., et al.
Publicado: (2020)

Metal–Metal Bonding in Uranium–Group 10 Complexes
por: Hlina, Johann A., et al.
Publicado: (2016)

Crystal structures of metallocene complexes with uranium–germanium bonds
por: Tarlton, Michael L., et al.
Publicado: (2021)

Rhodium-catalysed selective C–C bond activation and borylation of cyclopropanes
por: Wang, Yandong, et al.
Publicado: (2021)

Rhodium-catalyzed regioselective addition of the ortho C–H bond in aromatic amides to the C–C double bond in α,β-unsaturated γ-lactones and dihydrofurans
por: Shibata, Kaname, et al.
Publicado: (2016)

Characterizing Pressure-Induced Uranium C=H Agostic Bonds**
por: Arnold, Polly L, et al.
Publicado: (2015)

Isolation of a Uranium(III)‐Carbon Multiple Bond Complex
por: Su, Wei, et al.
Publicado: (2021)

Rhodium-Catalyzed Synthesis of Organosulfur Compounds Involving S-S Bond Cleavage of Disulfides and Sulfur
por: Arisawa, Mieko, et al.
Publicado: (2020)

Cannot write session to /tmp/vufind_sessions/sess_r5cu54clt89b51d5k3tp4sdg62