Cargando…

Divergent Elementoboration: 1,3‐Haloboration versus 1,1‐Carboboration of Propargyl Esters

This work showcases the 1,3‐haloboration reaction of alkynes in which boron and chlorine add to propargyl systems in a proposed sequential oxazoliumborate formation with subsequent ring‐opening and chloride migration. In addition, the functionalization of these propargyl esters with dimethyl groups...

Descripción completa

Detalles Bibliográficos
Autores principales: Wilkins, Lewis C., Soltani, Yashar, Lawson, James R., Slater, Ben, Melen, Rebecca L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6055811/
https://www.ncbi.nlm.nih.gov/pubmed/29700863
http://dx.doi.org/10.1002/chem.201801493