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Spontaneous Assembly of an Organic–Inorganic Nucleic Acid Z‐DNA Double‐Helix Structure

Herein, we report a hybrid polyoxometalate organic–inorganic compound, Na(2)[(HGMP)(2)Mo(5)O(15)]⋅7 H(2)O (1; where GMP=guanosine monophosphate), which spontaneously assembles into a structure with dimensions that are strikingly similar to those of the naturally occurring left‐handed Z‐form of DNA....

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Detalles Bibliográficos
Autores principales: Kulikov, Vladislav, Johnson, Naomi A. B., Surman, Andrew J., Hutin, Marie, Kelly, Sharon M., Hezwani, Mohammed, Long, De‐Liang, Meyer, Gerd, Cronin, Leroy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6057607/
https://www.ncbi.nlm.nih.gov/pubmed/27900812
http://dx.doi.org/10.1002/anie.201606658