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Higher activation barriers can lift exothermic rate restrictions in electron transfer and enable faster reactions

Electron transfer reactions are arguably the simplest chemical reactions but they have not yet ceased to intrigue chemists. Charge-separation and charge-recombination reactions are at the core of life-sustaining processes, molecular electronics and solar cells. Intramolecular electron donor-acceptor...

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Detalles Bibliográficos
Autores principales: Mentel, Kamila K., Serra, Arménio, Abreu, Paulo E., Arnaut, Luis G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6060101/
https://www.ncbi.nlm.nih.gov/pubmed/30046094
http://dx.doi.org/10.1038/s41467-018-05267-5