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Immediate hydroxylation of arenes to phenols via V-containing all-silica ZSM-22 zeolite triggered non-radical mechanism
Hydroxylation of arenes via activation of aromatic C(sp2)–H bond has attracted great attention for decades but remains a huge challenge. Herein, we achieve the ring hydroxylation of various arenes with stoichiometric hydrogen peroxide (H(2)O(2)) into the corresponding phenols on a robust heterogeneo...
Autores principales: | , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6062531/ https://www.ncbi.nlm.nih.gov/pubmed/30050071 http://dx.doi.org/10.1038/s41467-018-05351-w |