Cargando…

Immediate hydroxylation of arenes to phenols via V-containing all-silica ZSM-22 zeolite triggered non-radical mechanism

Hydroxylation of arenes via activation of aromatic C(sp2)–H bond has attracted great attention for decades but remains a huge challenge. Herein, we achieve the ring hydroxylation of various arenes with stoichiometric hydrogen peroxide (H(2)O(2)) into the corresponding phenols on a robust heterogeneo...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhou, Yu, Ma, Zhipan, Tang, Junjie, Yan, Ning, Du, Yonghua, Xi, Shibo, Wang, Kai, Zhang, Wei, Wen, Haimeng, Wang, Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6062531/
https://www.ncbi.nlm.nih.gov/pubmed/30050071
http://dx.doi.org/10.1038/s41467-018-05351-w