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Crystal structures of 2-bromo-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane and 2-bromo-1,1,1,3,3,3-hexaisopropyl-2-(triisopropylsilyl)trisilane
The synthesis and crystal structures of two tris(trialkylsilyl)silyl bromide compounds, C(9)H(27)BrSi(4) (I, HypSiBr) and C(27)H(63)BrSi(4) (II, TipSiBr), are described. Compound I was prepared in 85% yield by free-radical bromination of 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane us...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6072994/ https://www.ncbi.nlm.nih.gov/pubmed/30116580 http://dx.doi.org/10.1107/S2056989018009696 |