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Crystal structures of 2-bromo-1,1,1,3,3,3-hexa­methyl-2-(tri­methyl­sil­yl)tris­ilane and 2-bromo-1,1,1,3,3,3-hexa­isopropyl-2-(triiso­propyl­sil­yl)tri­silane

The synthesis and crystal structures of two tris­(tri­alkyl­sil­yl)silyl bromide compounds, C(9)H(27)BrSi(4) (I, HypSiBr) and C(27)H(63)BrSi(4) (II, TipSiBr), are described. Compound I was prepared in 85% yield by free-radical bromination of 1,1,1,3,3,3-hexa­methyl-2-(tri­methyl­sil­yl)tris­ilane us...

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Detalles Bibliográficos
Autores principales: Gulotty, Eva M., Staples, Richard J., Biros, Shannon M., Gaspar, Peter P., Rath, Nigam P., Winchester, William R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6072994/
https://www.ncbi.nlm.nih.gov/pubmed/30116580
http://dx.doi.org/10.1107/S2056989018009696