Forcing the reversibility of a mechanochemical reaction

Mechanical force modifies the free-energy surface of chemical reactions, often enabling thermodynamically unfavoured reaction pathways. Most of our molecular understanding of force-induced reactivity is restricted to the irreversible homolytic scission of covalent bonds and ring-opening in polymer m...

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Detalles Bibliográficos
Autores principales: Beedle, Amy E. M., Mora, Marc, Davis, Colin T., Snijders, Ambrosius P., Stirnemann, Guillaume, Garcia-Manyes, Sergi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6082871/
https://www.ncbi.nlm.nih.gov/pubmed/30089863
http://dx.doi.org/10.1038/s41467-018-05115-6

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6082871/
https://www.ncbi.nlm.nih.gov/pubmed/30089863
http://dx.doi.org/10.1038/s41467-018-05115-6

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