Platinum(iv) azido complexes undergo copper-free click reactions with alkynes

We report our investigations into the first examples of copper-free 1,3-dipolar cycloaddition (click) reactions of electrophiles with a Pt(IV) azido complex. The Pt-(IV) azido complex trans, trans, trans-[Pt(IV)(py)(2)(N(3))(2)(OH)(2)] (1) was reactive towards dimethyl acetylenedicarboxylate (DMAD)...

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Detalles Bibliográficos
Autores principales: Farrer, Nicola J., Sharma, Gitanjali, Sayers, Rachel, Shaili, Evyenia, Sadler, Peter J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6083821/
https://www.ncbi.nlm.nih.gov/pubmed/29480314
http://dx.doi.org/10.1039/c7dt04183g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6083821/
https://www.ncbi.nlm.nih.gov/pubmed/29480314
http://dx.doi.org/10.1039/c7dt04183g

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