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Viologen-modified electrodes for protection of hydrogenases from high potential inactivation while performing H(2) oxidation at low overpotential

In this work we present a viologen-modified electrode providing protection for hydrogenases against high potential inactivation. Hydrogenases, including O(2)-tolerant classes, suffer from reversible inactivation upon applying high potentials, which limits their use in biofuel cells to certain condit...

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Detalles Bibliográficos
Autores principales: Oughli, Alaa A., Vélez, Marisela, Birrell, James A., Schuhmann, Wolfgang, Lubitz, Wolfgang, Plumeré, Nicolas, Rüdiger, Olaf
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6083823/
https://www.ncbi.nlm.nih.gov/pubmed/29881850
http://dx.doi.org/10.1039/c8dt00955d