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N(2) activation on a molybdenum–titanium–sulfur cluster

The FeMo-cofactor of nitrogenase, a metal–sulfur cluster that contains eight transition metals, promotes the conversion of dinitrogen into ammonia when stored in the protein. Although various metal–sulfur clusters have been synthesized over the past decades, their use in the activation of N(2) has r...

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Detalles Bibliográficos
Autores principales: Ohki, Yasuhiro, Uchida, Keisuke, Tada, Mizuki, Cramer, Roger E., Ogura, Takashi, Ohta, Takehiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6086867/
https://www.ncbi.nlm.nih.gov/pubmed/30097563
http://dx.doi.org/10.1038/s41467-018-05630-6