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Re-evaluating how charge transfer modifies the conformation of adsorbed molecules

The archetypal electron acceptor molecule, TCNQ, is generally believed to become bent into an inverted bowl shape upon adsorption on the coinage metal surfaces on which it becomes negatively charged. New quantitative experimental structural measurements show that this is not the case for TCNQ on Ag(...

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Detalles Bibliográficos
Autores principales: Blowey, P. J., Velari, S., Rochford, L. A., Duncan, D. A., Warr, D. A., Lee, T.-L., De Vita, A., Costantini, G., Woodruff, D. P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6088372/
https://www.ncbi.nlm.nih.gov/pubmed/30051899
http://dx.doi.org/10.1039/c8nr02237b