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Site-selective formation of an iron(iv)–oxo species at the more electron-rich iron atom of heteroleptic μ-nitrido diiron phthalocyanines

Iron(iv)–oxo species have been identified as the active intermediates in key enzymatic processes, and their catalytic properties are strongly affected by the equatorial and axial ligands bound to the metal, but details of these effects are still unresolved. In our aim to create better and more effic...

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Detalles Bibliográficos
Autores principales: İşci, Ümit, Faponle, Abayomi S., Afanasiev, Pavel, Albrieux, Florian, Briois, Valérie, Ahsen, Vefa, Dumoulin, Fabienne, Sorokin, Alexander B., de Visser, Sam P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6088558/
https://www.ncbi.nlm.nih.gov/pubmed/30155008
http://dx.doi.org/10.1039/c5sc01811k