Cargando…

Mechanistic studies on the addition of hydrogen to iridaepoxide complexes with subsequent elimination of water

Iridium complexes of the PC(sp(2))P ligand in which the donors are linked by 2,3-benzo[b]thiophene groups engage in the cooperative activation of N(2)O and the resulting iridaepoxides can be treated with dihydrogen to effect elimination of water and regeneration of the starting iridium complex. The...

Descripción completa

Detalles Bibliográficos
Autores principales: Doyle, Lauren E., Piers, Warren E., Borau-Garcia, Javier, Sgro, Michael J., Spasyuk, Denis M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6090529/
https://www.ncbi.nlm.nih.gov/pubmed/30155011
http://dx.doi.org/10.1039/c5sc03575a