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Mechanistic studies on the addition of hydrogen to iridaepoxide complexes with subsequent elimination of water
Iridium complexes of the PC(sp(2))P ligand in which the donors are linked by 2,3-benzo[b]thiophene groups engage in the cooperative activation of N(2)O and the resulting iridaepoxides can be treated with dihydrogen to effect elimination of water and regeneration of the starting iridium complex. The...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6090529/ https://www.ncbi.nlm.nih.gov/pubmed/30155011 http://dx.doi.org/10.1039/c5sc03575a |