Hydrodeoxygenation of isocyanates: snapshots of a magnesium-mediated C[double bond, length as m-dash]O bond cleavage

Organic isocyanates are readily converted to methyl amine products through their hydroboration with HBpin in the presence of a β-diketiminato magnesium catalyst. Although borylated amide and N-,O-bis(boryl)hemiaminal species have been identified as intermediates during the reductive catalysis, the o...

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Detalles Bibliográficos
Autores principales: Yang, Yan, Anker, Mathew D., Fang, Jian, Mahon, Mary F., Maron, Laurent, Weetman, Catherine, Hill, Michael S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6092714/
https://www.ncbi.nlm.nih.gov/pubmed/30155199
http://dx.doi.org/10.1039/c7sc00117g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6092714/
https://www.ncbi.nlm.nih.gov/pubmed/30155199
http://dx.doi.org/10.1039/c7sc00117g

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