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Hydrodeoxygenation of isocyanates: snapshots of a magnesium-mediated C[double bond, length as m-dash]O bond cleavage

Organic isocyanates are readily converted to methyl amine products through their hydroboration with HBpin in the presence of a β-diketiminato magnesium catalyst. Although borylated amide and N-,O-bis(boryl)hemiaminal species have been identified as intermediates during the reductive catalysis, the o...

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Detalles Bibliográficos
Autores principales:	Yang, Yan, Anker, Mathew D., Fang, Jian, Mahon, Mary F., Maron, Laurent, Weetman, Catherine, Hill, Michael S.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2017
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6092714/ https://www.ncbi.nlm.nih.gov/pubmed/30155199 http://dx.doi.org/10.1039/c7sc00117g

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