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Efficient and selective hydrogenation of amides to alcohols and amines using a well-defined manganese–PNN pincer complex

Novel well-defined NNP and PNP manganese pincer complexes have been synthetized and fully characterized. The catalyst Mn-2 containing an imidazolyaminolphosphino ligand shows high activity and selectivity in the hydrogenation of a wide range of secondary and tertiary amides to the corresponding alco...

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Detalles Bibliográficos
Autores principales: Papa, Veronica, Cabrero-Antonino, Jose R., Alberico, Elisabetta, Spanneberg, Anke, Junge, Kathrin, Junge, Henrik, Beller, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6092716/
https://www.ncbi.nlm.nih.gov/pubmed/30155202
http://dx.doi.org/10.1039/c7sc00138j