Imposing high-symmetry and tuneable geometry on lanthanide centres with chelating Pt and Pd metalloligands

Exploitation of HSAB preferences allows for high-yield, one-pot syntheses of lanthanide complexes chelated by two Pd or Pt metalloligands, [M(II)(SAc)(4)](2–) (SAc(–) = thioacetate, M = Pd, Pt). The resulting complexes with 8 oxygen donors surrounding the lanthanides can be isolated in crystallograp...

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Detalles Bibliográficos
Autores principales: Sørensen, Mikkel A., Weihe, Høgni, Vinum, Morten G., Mortensen, Jesper S., Doerrer, Linda H., Bendix, Jesper
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6092721/
https://www.ncbi.nlm.nih.gov/pubmed/30155201
http://dx.doi.org/10.1039/c7sc00135e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6092721/
https://www.ncbi.nlm.nih.gov/pubmed/30155201
http://dx.doi.org/10.1039/c7sc00135e

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