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Imposing high-symmetry and tuneable geometry on lanthanide centres with chelating Pt and Pd metalloligands
Exploitation of HSAB preferences allows for high-yield, one-pot syntheses of lanthanide complexes chelated by two Pd or Pt metalloligands, [M(II)(SAc)(4)](2–) (SAc(–) = thioacetate, M = Pd, Pt). The resulting complexes with 8 oxygen donors surrounding the lanthanides can be isolated in crystallograp...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6092721/ https://www.ncbi.nlm.nih.gov/pubmed/30155201 http://dx.doi.org/10.1039/c7sc00135e |