Multi-electron reduction of sulfur and carbon disulfide using binuclear uranium(iii) borohydride complexes

The first use of a dinuclear U(III)/U(III) complex in the activation of small molecules is reported. The octadentate Schiff-base pyrrole, anthracene-hinged ‘Pacman’ ligand L(A) combines two strongly reducing U(III) centres and three borohydride ligands in [M(THF)(4)][{U(BH(4))}(2)(μ-BH(4))(L(A))(THF...

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Detalles Bibliográficos
Autores principales: Arnold, Polly L., Stevens, Charlotte J., Bell, Nicola L., Lord, Rianne M., Goldberg, Jonathan M., Nichol, Gary S., Love, Jason B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6094157/
https://www.ncbi.nlm.nih.gov/pubmed/30155206
http://dx.doi.org/10.1039/c7sc00382j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6094157/
https://www.ncbi.nlm.nih.gov/pubmed/30155206
http://dx.doi.org/10.1039/c7sc00382j

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