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Multi-electron reduction of sulfur and carbon disulfide using binuclear uranium(iii) borohydride complexes
The first use of a dinuclear U(III)/U(III) complex in the activation of small molecules is reported. The octadentate Schiff-base pyrrole, anthracene-hinged ‘Pacman’ ligand L(A) combines two strongly reducing U(III) centres and three borohydride ligands in [M(THF)(4)][{U(BH(4))}(2)(μ-BH(4))(L(A))(THF...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6094157/ https://www.ncbi.nlm.nih.gov/pubmed/30155206 http://dx.doi.org/10.1039/c7sc00382j |