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Symmetry breakdown of 4,4″-diamino-p-terphenyl on a Cu(111) surface by lattice mismatch

Site-selective functionalization of only one of two identical chemical groups within one molecule is highly challenging, which hinders the production of complex organic macromolecules. Here we demonstrate that adsorption of 4,4″-diamino-p-terphenyl on a metal surface leads to a dissymmetric binding...

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Detalles Bibliográficos
Autores principales: Zhong, Qigang, Ebeling, Daniel, Tschakert, Jalmar, Gao, Yixuan, Bao, Deliang, Du, Shixuan, Li, Chen, Chi, Lifeng, Schirmeisen, André
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6095862/
https://www.ncbi.nlm.nih.gov/pubmed/30115915
http://dx.doi.org/10.1038/s41467-018-05719-y