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Enantioselective radical conjugate additions driven by a photoactive intramolecular iminium-ion-based EDA complex

The photochemical activity of electron donor–acceptor (EDA) complexes provides a way to generate radicals under mild conditions. This strategy has found application in chemical synthesis and recently in enantioselective catalysis. Reported methods classically relied on the formation of intermolecula...

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Detalles Bibliográficos
Autores principales: Cao, Zhong-Yan, Ghosh, Tamal, Melchiorre, Paolo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6095928/
https://www.ncbi.nlm.nih.gov/pubmed/30115906
http://dx.doi.org/10.1038/s41467-018-05375-2