Post‐Synthetic Mannich Chemistry on Metal‐Organic Frameworks: System‐Specific Reactivity and Functionality‐Triggered Dissolution

The Mannich reaction of the zirconium MOF [Zr(6)O(4)(OH)(4)(bdc‐NH(2))(6)] (UiO‐66‐NH(2), bdc‐NH(2)=2‐amino‐1,4‐benzenedicarboxylate) with paraformaldehyde and pyrazole, imidazole or 2‐mercaptoimidazole led to post‐synthetic modification (PSM) through C−N bond formation. The reaction with imidazole...

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Detalles Bibliográficos
Autores principales: Amer Hamzah, Harina, Gee, William J., Raithby, Paul R., Teat, Simon J., Mahon, Mary F., Burrows, Andrew D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6099314/
https://www.ncbi.nlm.nih.gov/pubmed/29808942
http://dx.doi.org/10.1002/chem.201801419

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6099314/
https://www.ncbi.nlm.nih.gov/pubmed/29808942
http://dx.doi.org/10.1002/chem.201801419

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