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Post‐Synthetic Mannich Chemistry on Metal‐Organic Frameworks: System‐Specific Reactivity and Functionality‐Triggered Dissolution
The Mannich reaction of the zirconium MOF [Zr(6)O(4)(OH)(4)(bdc‐NH(2))(6)] (UiO‐66‐NH(2), bdc‐NH(2)=2‐amino‐1,4‐benzenedicarboxylate) with paraformaldehyde and pyrazole, imidazole or 2‐mercaptoimidazole led to post‐synthetic modification (PSM) through C−N bond formation. The reaction with imidazole...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6099314/ https://www.ncbi.nlm.nih.gov/pubmed/29808942 http://dx.doi.org/10.1002/chem.201801419 |