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A Dipyrrin Programmed for Covalent Loading with Fullerenes

We describe here a di‐(β,β′‐sulfoleno)pyrrin programmed for efficient and specific β,β′‐functionalization via [4+2] cycloaddition reactions. At 120 °C and in the presence of an excess of C(60)‐fullerene the di‐(β,β′‐sulfoleno)pyrrin decomposed cleanly, furnishing a di‐(β,β′‐fullereno)pyrrin and the...

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Detalles Bibliográficos
Autores principales: Li, Chengjie, Wurst, Klaus, Kräutler, Bernhard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6099335/
https://www.ncbi.nlm.nih.gov/pubmed/29802661
http://dx.doi.org/10.1002/chem.201801995