Comparing Neutral (Monometallic) and Anionic (Bimetallic) Aluminum Complexes in Hydroboration Catalysis: Influences of Lithium Cooperation and Ligand Set

Bimetallic lithium aluminates and neutral aluminum counterparts are compared as catalysts in hydroboration reactions with aldehydes, ketones, imines and alkynes. Possessing Li–Al cooperativity, ate catalysts are found to be generally superior. Catalytic activity is also influenced by the ligand set,...

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Detalles Bibliográficos
Autores principales: Pollard, Victoria A., Fuentes, M. Ángeles, Kennedy, Alan R., McLellan, Ross, Mulvey, Robert E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6099445/
https://www.ncbi.nlm.nih.gov/pubmed/29906339
http://dx.doi.org/10.1002/anie.201806168

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6099445/
https://www.ncbi.nlm.nih.gov/pubmed/29906339
http://dx.doi.org/10.1002/anie.201806168

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