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Comparing Neutral (Monometallic) and Anionic (Bimetallic) Aluminum Complexes in Hydroboration Catalysis: Influences of Lithium Cooperation and Ligand Set
Bimetallic lithium aluminates and neutral aluminum counterparts are compared as catalysts in hydroboration reactions with aldehydes, ketones, imines and alkynes. Possessing Li–Al cooperativity, ate catalysts are found to be generally superior. Catalytic activity is also influenced by the ligand set,...
Autores principales: | Pollard, Victoria A., Fuentes, M. Ángeles, Kennedy, Alan R., McLellan, Ross, Mulvey, Robert E. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6099445/ https://www.ncbi.nlm.nih.gov/pubmed/29906339 http://dx.doi.org/10.1002/anie.201806168 |
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