Cobalt(II) Complexes with N,N,N-Scorpionates and Bidentate Ligands: Comparison of Hydrotris(3,5-dimethylpyrazol-1-yl)borate Tp* vs. Phenyltris(4,4-dimethyloxazolin-2-yl)borate To(M) to Control the Structural Properties and Reactivities of Cobalt Centers

Scorpionate ligands Tp* (hydrotris(3,5-dimethylpyrazol-1-yl)borate) and To(M) (tris(4,4-dimethyloxazolin-2-yl)phenylborate) complexes of cobalt(II) with bidentate ligands were synthesized. Both Tp* and To(M) coordinate to cobalt(II) in a tridentate fashion when the bidentate ligand is the less hinde...

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Detalles Bibliográficos
Autores principales: Nishiura, Toshiki, Uramoto, Takahiro, Takiyama, Yuichiro, Nakazawa, Jun, Hikichi, Shiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6099786/
https://www.ncbi.nlm.nih.gov/pubmed/29914171
http://dx.doi.org/10.3390/molecules23061466

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6099786/
https://www.ncbi.nlm.nih.gov/pubmed/29914171
http://dx.doi.org/10.3390/molecules23061466

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