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Reactivity studies on [Cp′Fe(μ-I)](2): nitrido-, sulfido- and diselenide iron complexes derived from pseudohalide activation
The iron half-sandwich [Cp′Fe(μ-I)](2) (Cp′ = 1,2,4-(Me(3)C)(3)C(5)H(2), 1) reacts with the pseudohalides NCO(–), SCN(–), SeCN(–) and N(3)(–) to give [Cp′Fe(μ-NCO)](2) (2), [Cp′Fe(μ-S)](2) (3), [Cp′Fe(μ-Se(2))](2) (4) and [Cp′Fe(μ-N)](2) (5), respectively. Various spectroscopic techniques including...
Autores principales: | , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6099922/ https://www.ncbi.nlm.nih.gov/pubmed/30155215 http://dx.doi.org/10.1039/c7sc00570a |