Reactivity studies on [Cp′Fe(μ-I)](2): nitrido-, sulfido- and diselenide iron complexes derived from pseudohalide activation

The iron half-sandwich [Cp′Fe(μ-I)](2) (Cp′ = 1,2,4-(Me(3)C)(3)C(5)H(2), 1) reacts with the pseudohalides NCO(–), SCN(–), SeCN(–) and N(3)(–) to give [Cp′Fe(μ-NCO)](2) (2), [Cp′Fe(μ-S)](2) (3), [Cp′Fe(μ-Se(2))](2) (4) and [Cp′Fe(μ-N)](2) (5), respectively. Various spectroscopic techniques including...

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Detalles Bibliográficos
Autores principales: Reiners, Matthias, Maekawa, Miyuki, Daniliuc, Constantin G., Freytag, Matthias, Jones, Peter G., White, Peter S., Hohenberger, Johannes, Sutter, Jörg, Meyer, Karsten, Maron, Laurent, Walter, Marc D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6099922/
https://www.ncbi.nlm.nih.gov/pubmed/30155215
http://dx.doi.org/10.1039/c7sc00570a

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