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Highly Electrophilic, Catalytically Active and Redox‐Responsive Cobaltoceniumyl and Ferrocenyl Triazolylidene Coinage Metal Complexes

A convenient access to a triad of triazoles with ferrocenyl and cobaltoceniumyl substituents is reported. N‐Alkylation, deprotonation and metalation with Cu(I)/Ag(I)/Au(I) synthons affords the heteroleptic triazolylidene complexes. Due to the combination of neutral, electron‐donating ferrocenyl subs...

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Detalles Bibliográficos
Autores principales: Vanicek, Stefan, Podewitz, Maren, Stubbe, Jessica, Schulze, Dennis, Kopacka, Holger, Wurst, Klaus, Müller, Thomas, Lippmann, Petra, Haslinger, Simone, Schottenberger, Herwig, Liedl, Klaus R., Ott, Ingo, Sarkar, Biprajit, Bildstein, Benno
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6100101/
https://www.ncbi.nlm.nih.gov/pubmed/29214677
http://dx.doi.org/10.1002/chem.201705051