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Highly Electrophilic, Catalytically Active and Redox‐Responsive Cobaltoceniumyl and Ferrocenyl Triazolylidene Coinage Metal Complexes
A convenient access to a triad of triazoles with ferrocenyl and cobaltoceniumyl substituents is reported. N‐Alkylation, deprotonation and metalation with Cu(I)/Ag(I)/Au(I) synthons affords the heteroleptic triazolylidene complexes. Due to the combination of neutral, electron‐donating ferrocenyl subs...
Autores principales: | Vanicek, Stefan, Podewitz, Maren, Stubbe, Jessica, Schulze, Dennis, Kopacka, Holger, Wurst, Klaus, Müller, Thomas, Lippmann, Petra, Haslinger, Simone, Schottenberger, Herwig, Liedl, Klaus R., Ott, Ingo, Sarkar, Biprajit, Bildstein, Benno |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6100101/ https://www.ncbi.nlm.nih.gov/pubmed/29214677 http://dx.doi.org/10.1002/chem.201705051 |
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