Tris[(1-isopropylbenzimidazol-2-yl)dimethylsilyl]methyl metal complexes, [Tism(Pr(i)Benz)]M: a new class of metallacarbatranes, isomerization to a tris(N-heterocyclic carbene) derivative, and evidence for an inverted ligand field

The tris[(1-isopropylbenzimidazol-2-yl)dimethylsilyl]methyl ligand, [Tism(Pr(i)Benz)], has been employed to form carbatrane compounds of both the main group metals and transition metals, namely [Tism(Pr(i)Benz)]Li, [Tism(Pr(i)Benz)]MgMe, [Tism(Pr(i)Benz)]Cu and [Tism(Pr(i)Benz)]NiBr. In addition to...

Descripción completa

Detalles Bibliográficos
Autores principales: Ruccolo, Serge, Rauch, Michael, Parkin, Gerard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6100236/
https://www.ncbi.nlm.nih.gov/pubmed/30155219
http://dx.doi.org/10.1039/c7sc00499k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6100236/
https://www.ncbi.nlm.nih.gov/pubmed/30155219
http://dx.doi.org/10.1039/c7sc00499k

Ejemplares similares