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Tris[(1-isopropylbenzimidazol-2-yl)dimethylsilyl]methyl metal complexes, [Tism(Pr(i)Benz)]M: a new class of metallacarbatranes, isomerization to a tris(N-heterocyclic carbene) derivative, and evidence for an inverted ligand field
The tris[(1-isopropylbenzimidazol-2-yl)dimethylsilyl]methyl ligand, [Tism(Pr(i)Benz)], has been employed to form carbatrane compounds of both the main group metals and transition metals, namely [Tism(Pr(i)Benz)]Li, [Tism(Pr(i)Benz)]MgMe, [Tism(Pr(i)Benz)]Cu and [Tism(Pr(i)Benz)]NiBr. In addition to...
Autores principales: | Ruccolo, Serge, Rauch, Michael, Parkin, Gerard |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6100236/ https://www.ncbi.nlm.nih.gov/pubmed/30155219 http://dx.doi.org/10.1039/c7sc00499k |
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