Molybdenum-Catalyzed Enantioselective Sulfoxidation Controlled by a Nonclassical Hydrogen Bond between Coordinated Chiral Imidazolium-Based Dicarboxylate and Peroxido Ligands

Chiral alkyl aryl sulfoxides were obtained by molybdenum-catalyzed oxidation of alkyl aryl sulfides with hydrogen peroxide as oxidant in mild conditions with high yields and moderate enantioselectivities. The asymmetry is generated by the use of imidazolium-based dicarboxylic compounds, HL(R). The i...

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Detalles Bibliográficos
Autores principales: Carrasco, Carlos J., Montilla, Francisco, Galindo, Agustín
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6100257/
https://www.ncbi.nlm.nih.gov/pubmed/29966332
http://dx.doi.org/10.3390/molecules23071595

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6100257/
https://www.ncbi.nlm.nih.gov/pubmed/29966332
http://dx.doi.org/10.3390/molecules23071595

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