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Comparison between Tetrel Bonded Complexes Stabilized by σ and π Hole Interactions
The σ-hole tetrel bonds formed by a tetravalent molecule are compared with those involving a π-hole above the tetrel atom in a trivalent bonding situation. The former are modeled by TH(4), TH(3)F, and TH(2)F(2) (T = Si, Ge, Sn) and the latter by TH(2)=CH(2), THF=CH(2), and TF(2)=CH(2), all paired wi...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6100375/ https://www.ncbi.nlm.nih.gov/pubmed/29891824 http://dx.doi.org/10.3390/molecules23061416 |