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KO(t)Bu as a Single Electron Donor? Revisiting the Halogenation of Alkanes with CBr(4) and CCl(4)

The search for reactions where KO(t)Bu and other tert-alkoxides might behave as single electron donors led us to explore their reactions with tetrahalomethanes, CX(4), in the presence of adamantane. We recently reported the halogenation of adamantane under these conditions. These reactions appeared...

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Detalles Bibliográficos
Autores principales: Emery, Katie J., Young, Allan, Arokianathar, J. Norman, Tuttle, Tell, Murphy, John A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6102552/
https://www.ncbi.nlm.nih.gov/pubmed/29724009
http://dx.doi.org/10.3390/molecules23051055