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Force-induced retro-click reaction of triazoles competes with adjacent single-bond rupture
The highly controversial force-induced cycloreversion of 1,2,3-triazole, its well-known retro-click reaction, is shown to be possible only for 1,5-substituted triazoles, but competes with rupture of an adjacent single-bond. We draw this conclusion from both static and dynamic calculations under exte...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Royal Society of Chemistry
2017
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6103003/ https://www.ncbi.nlm.nih.gov/pubmed/30155228 http://dx.doi.org/10.1039/c7sc01562c |