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Conjugated double helices via self-dimerization of α,α′-dianilinotripyrrins

A new motif for artificial double helices was developed on the basis of α,α′-disubstituted tripyrrin. α,α′-Dibromotripyrrin 3 was prepared by gentle bromination at the pyrrolic α-positions of 5,10-diphenyltripyrrane followed by oxidation with DDQ. Nucleophilic substitution reactions of 3 with anilin...

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Detalles Bibliográficos
Autores principales: Umetani, Masataka, Tanaka, Takayuki, Osuka, Atsuhiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6114996/
https://www.ncbi.nlm.nih.gov/pubmed/30310618
http://dx.doi.org/10.1039/c8sc02739k